Reinvestigation of trisodium dihydroxidotetraoxidoneptunate(VII) dihydrate

Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate

The title compound, Na(3)[NpO(4)(OH)(2)]·2H(2)O, contains distorted tetra-gonal-bipyramidal centrosymmetric [NpO(4)(OH)(2)](3-) complex anions. The Np-O distances are 1.8975 (7) and 1.8891 (7) Å in the NpO(4) group and 2.3451 (7) Å to the OH group. Both Na atoms (one in a general position, the second in a special position on an inversion centre) have a distorted octahedral oxygen environment.

EPR and Optical Absorption Studies of VO2+ Doped Trisodium Citrate Dihydrate Single Crystals

The electron paramagnetic resonance of VO2+ doped trisodium citrate dihydrate (Na3C6H5O7·2H2O) single crystals and powder has been examined at room temperature. The angular variation of the EPR spectra has shown that two different VO2+ complexes are located in different chemical environments, each environment containing two magnetically inequivalent VO2+ sites in distinct orientations occupying...

Trisodium scandium bis­(orthoborate)

Single crystals of tris-odium scandium bis-(orthoborate), Na(3)Sc(BO(3))(2), have been obtained by spontaneous crystallization from an Na(2)O-Sc(2)O(3)-B(2)O(3) melt. The crystal structure features a three-dimensional framework composed of planar [BO(3)](3-) groups and distorted ScO(6) octa-hedra with Na atoms in the cavities. The Sc atom occupies a special position (Wyckoff position 2b, site s...

Trisodium citrate, Na3(C6H5O7)

The crystal structure of anhydrous tris-odium citrate, Na3(C6H5O7), has been solved and refined using synchrotron X-ray powder diffraction data, and optimized using density functional theory (DFT). There are two independent five-coordinate Na(+) and one six-coordinate Na(+) cations in the asymmetric unit. The [NaO5] and [NaO6] polyhedra share edges and corners to form a three-dimensional framew...

OPINION ON Trisodium nitrilotriacetate (NTA)